For me Photoshop is a tool to bridge the gap between what the human experienc is...and what the camera is capable of recording. I always try to maximize what the camera can do first....but always consider what photoshop can do with that maximized information as well but that thought is a blended second into the first priority.

In short....ALWAYS maximize the camera...(proper WB (even if shooting RAW) proper exposure, etc) then apply your Photoshop pre visualization.

SOrry if this seems repetitive..but always on guard to preventing the idea of many who often say "ahh...I can fix it later in photoshop" is all.

My wording while subtly diffrent but very important is "ahh....I think I can really make this sing with photoshop" as I am confident I have the most info I can capture.

Sorry about the little pet peeve rant...climbing back down off my soap box...LOL!!!

Roman